Research evaluation of some properties of HDX-24 porous metal mechanical frame material
DOI:
https://doi.org/10.54939/1859-1043.j.mst.99.2024.61-68Keywords:
HDX-24 material; MOFs; H4L.Abstract
This paper introduces the results of the research on the fabrication of HDX-24 porous metal-mechanical framework material using 4,4'-Bipyridine-2,6,2',6'-tetracarboxylic acid (H4L). The properties of post-fabrication materials are studied through a number of modern research methods such as Scanning electron microscopy (FE-SEM), BET-specific surface area determination, TGA thermogravimetric analysis, X-ray diffraction spectroscopy (XRD), X-ray energy scattering spectroscopy (EDS), etc. Fourier Transform Infrared Spectroscopy (FT-IR). The results show that HDX-24 material has a specific surface area-BET of 239.06 m2/g, the adsorption capacity of the material reaches 5.2 mmol/g, the particle size reaches 75-78 mm, and the pore volume is 0.202 cm3/g.
References
[1]. Jiangnan Li, Xue Han, Xinran Zhang, Alena M. Sheveleva, Yongqiang Cheng, Floriana Tuna, Eric J. L. Mc Innes , “Capture of nitrogen dioxide and conversion to nitric acid in a porous metal-organic framework”, Nature Chemistry, Vol 11, pp. 1085–1090, (2019).
[2]. Chao Liu, Jing Wang, Jingjing Wan, Chengzhong Yu, “MOF-on-MOF hybrids: Synthesis and applications”, Coordination Chemistry Reviews, Vol 432, pp. 1051-1064 (2021).
[3]. Aysha Al Obeidli, Haifa Ben Salah, Mohammed Al Murisi, Rana Sabouni, “Recent advancements in MOFs synthesis and their green applications “, International Journal of Hydrogen Energy, Vol 47, pp. 2561-2593, (2022).
[4]. Shunsuke Tanaka, “Chapter 10 - Mechanochemical synthesis of MOFs”, Metal-Organic Frameworks for Biomedical Applications, Vol 10, pp. 197-222, (2020).
[5]. Chandan Dey, Tanay Kundu, Bishnu P. Biswal, Arijit Mallick, Rahul Banerjee, “Crystalline metal-organic frameworks (MOFs): synthesis, structure and function”, Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, Vol 70, pp. 3-10, (2014).
[6]. Wei Chen, Liping Du, Chunsheng Wu, “Chapter 7 - Hydrothermal synthesis of MOFs”, Metal-Organic Frameworks for Biomedical Applications, Vol 7, pp. 141-157, (2020).